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稳定化α-Ni(OH)2电化学性能的研究
ELECTROCHEMICAL PERFORMANCE OF STABLE α-Ni(OH)2
【摘要】 为了得到比能量高、晶型稳定的α—Ni(OH ) 2 ,使用恒流放电方法 ,研究了添加剂Al,Co对α—Ni(OH) 2 电化学性能的影响 .实验表明 ,添加Al的α—Ni(OH) 2 比容量高于 β Ni(OH) 2 的理论比容量 .Al,Co的添加对α—Ni(OH) 2 的比容量和放电电压有影响 .Al含量的增加提高了α—Ni(OH)的放电电压 .Al含量为2 0 %的α -Ni(OH) 2 比容量最高
【Abstract】 In order to obtain stable α-Ni(OH) 2 with high specific energy,the effects of doped elements Al and Co on the electrochemical performance of α-Ni(OH) 2 were studied.Based on the study,we found that the practical discharge specific capacity of α-Ni(OH) 2 doped with Al was higher than the theoretical discharge specific capacity of βNi(OH) 2 and the discharge specific capacity and discharge potential of α-Ni(OH) 2 were greatly affected by doped elements Al and Co.The discharge potential was improved with increasing content of Al.The highest discharge specific capacity of α-Ni(OH) 2 was obtained when the content of AI was20%.
【Key words】 nickel hydroxide with α crystal; nickel electrode; MH-Ni battery;
- 【文献出处】 哈尔滨工程大学学报 ,Journal of Harbin Engineering University , 编辑部邮箱 ,2001年02期
- 【分类号】TM911
- 【被引频次】6
- 【下载频次】87