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锡偶联型溶聚丁苯橡胶的流变性能

Rheological properties of Sn-coupled SSBR

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【作者】 王珍赵素合

【Author】 Wang Zhen, Zhao Suhe(College of Materials Science and Engineering,Beijing University of Chemical Technology,Beijing 100029,China)

【机构】 北京化工大学材料科学与工程学院北京化工大学材料科学与工程学院 北京100029北京100029

【摘要】 研究了锡偶联型溶聚丁苯橡胶(SSBR)生胶及其混炼胶的流变性能,并与乳聚丁苯橡胶(ESBR)作了对比。结果表明,锡偶联型SSBR生胶及混炼胶均属切力变稀的假塑性流体,混炼胶对剪切速率和温度的敏感性比生胶强。SSBR混炼胶对剪切速度的敏感性比ESBR混炼胶的强。挤出胀大效应表明锡偶联型SSBR混炼胶的弛豫速度比ESBR混炼胶的快,挤出胀大小,加工性能优于ESBR。

【Abstract】 The rheological properties of Sn-coupled SSBR raw and compound were studied and compared with ESBR. The result showed that both the raw and compound of Sn-coupled SSBR were pseudo-plastic fluid with shear stress, Sn-coupled SSBR compound was more sensible to shear rate and temperature than Sn-coupled SSBR raw,and was more sensible to shear rate than ESBR. Die swell of extrudate indicated that the relaxation rate of Sn-coupled SSBR compound was faster and the die swell was less obvious than that of ESBR.

【基金】 北京市基金委资助项目(2982015)
  • 【文献出处】 合成橡胶工业 ,China Synthetic Rubber Industry , 编辑部邮箱 ,2001年06期
  • 【分类号】TQ333.1
  • 【被引频次】19
  • 【下载频次】152
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