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锡偶联型溶聚丁苯橡胶的流变性能
Rheological properties of Sn-coupled SSBR
【摘要】 研究了锡偶联型溶聚丁苯橡胶(SSBR)生胶及其混炼胶的流变性能,并与乳聚丁苯橡胶(ESBR)作了对比。结果表明,锡偶联型SSBR生胶及混炼胶均属切力变稀的假塑性流体,混炼胶对剪切速率和温度的敏感性比生胶强。SSBR混炼胶对剪切速度的敏感性比ESBR混炼胶的强。挤出胀大效应表明锡偶联型SSBR混炼胶的弛豫速度比ESBR混炼胶的快,挤出胀大小,加工性能优于ESBR。
【Abstract】 The rheological properties of Sn-coupled SSBR raw and compound were studied and compared with ESBR. The result showed that both the raw and compound of Sn-coupled SSBR were pseudo-plastic fluid with shear stress, Sn-coupled SSBR compound was more sensible to shear rate and temperature than Sn-coupled SSBR raw,and was more sensible to shear rate than ESBR. Die swell of extrudate indicated that the relaxation rate of Sn-coupled SSBR compound was faster and the die swell was less obvious than that of ESBR.
【关键词】 锡偶联型溶聚丁苯橡胶;
乳聚丁苯橡胶;
流变性能;
挤出膨胀率;
【Key words】 Sn-coupled solution polymerized butadiene-styrene rubber; emulsion polymerized butadiene-styrene rubber; rheological property; die swell;
【Key words】 Sn-coupled solution polymerized butadiene-styrene rubber; emulsion polymerized butadiene-styrene rubber; rheological property; die swell;
【基金】 北京市基金委资助项目(2982015)
- 【文献出处】 合成橡胶工业 ,China Synthetic Rubber Industry , 编辑部邮箱 ,2001年06期
- 【分类号】TQ333.1
- 【被引频次】19
- 【下载频次】152