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EPDM与马来酸酐的反应挤出接枝
Study on preparation of EPDM grafted with maleic anhydride by reactive extrusion
【摘要】 用同向双螺杆挤出机,对三元乙丙共聚物(EPDM)进行熔融接枝马来酸酐(MAH),考察了单体、引发剂(DCP)用量和加工条件对接枝率的影响。结果表明,在EPDM接枝MAH的反应中,随着DCP用量的增加,接枝率增大;随着MAH用量的增加,接枝率趋于一个平衡值。较佳的实验配方为EPDM:MAH:DCP=100:1:0.03。
【Abstract】 The melt grafting of maleic anhydride (MAH) onto ethylene propylene diene mischpolymere (EPDM) was carried out via reactive extrusion by twin screw extruder. The effects of various parameters such as MAH, initiator (DCP) concentration and process condition on grafting yield were studied. The results showed that the grafting ratio increased with the increase of DCP content while the grafting ratio came to a constant as MAH content increased. The optimum formula was EPDM : MAH : DCP = 100 : 1 : 0.03.
【关键词】 反应挤出;
接枝;
三元乙丙共聚物;
马来酸酐;
引发剂;
【Key words】 reactive extrusion; grafting; ethylene propylene diene mischpolymere; maleic anhydride; initiator;
【Key words】 reactive extrusion; grafting; ethylene propylene diene mischpolymere; maleic anhydride; initiator;
- 【文献出处】 合成树脂及塑料 ,China Synthetic Resin and Plastics , 编辑部邮箱 ,2001年01期
- 【分类号】TQ323
- 【被引频次】16
- 【下载频次】276