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两种新型对称卟啉的合成及紫外可见光谱特性研究
Synthesis and Ultraviolet-Visible Spectrum of Two New Symmetrical Porphyrins
【摘要】 本文采用一种新型的合成方法合成了两种新型对称卟啉meso 四 (对苯甲酰胺基苯基 )卟啉和meso 四 (邻苯甲酰胺基苯基 )卟啉。用元素分析、红外光谱、核磁共振谱对两种卟啉进行了表征。并对其紫外可见光谱特性进行了研究。
【Abstract】 Meso tetra(p benzoylaminophenyl) porphyrin or meso tetra (o benzoylaminophenyl) porphyrin are synthesized by condensation of meso tetra (p aminophenyl) porphyrin or meso tetra (o aminophenyl) porphyrin and benzoyl chloride in DMF using NaOH as catalyst,these porphyrins and the method have not been reported previously.Their structures are ascertained by elemental analysis,ultraviolet visible spectrum,IR and 1H NMR measurements.The ultraviolet visible spectrum of the two porphyrins is discussed in detail.
【关键词】 对称卟啉;
合成;
紫外可见光谱;
【Key words】 Symmetrical porphyrins; Synthesis; Ultraviolet visible spectrum;
【Key words】 Symmetrical porphyrins; Synthesis; Ultraviolet visible spectrum;
【基金】 甘肃省自然科学基金资助课题
- 【文献出处】 光谱学与光谱分析 ,Spectroscopy and Spectral Analysis , 编辑部邮箱 ,2001年04期
- 【分类号】O657.3
- 【被引频次】11
- 【下载频次】243