【摘要】 合成了一种新的三桥连双铁 (III)配合物 [Fe2 (IDB) 2 (O) (CH3CO2 ) 2 ]Cl2 ·CH3OH ,IDB为N ,N’ -di(2’ -benzimidazolylmethyl)imine,利用单晶X射线衍射及其它谱学方法对所合成配合物进行了表征。每个双核单元的两个铁原子均通过一个氧原子和两个醋酸根连接 ,每个铁原子同时还与位于桥氧原子对位的三齿配体IDB重脂肪链上氮原子相结合 ,每个铁 (III)中心为一变形八面体结构。对该新化合物的拉曼光谱进行了研究并对一些谱峰进行了归属更多还原

【Abstract】 A triply bridged dirron (Ⅲ) complex [Fe 2(IDB) 2(O)(CH 3CO 2) 2]Cl 2 CH 3OH, in which IDB is N, N’-di(2’-benzimidazolyl methyl) imine, has been synthesized and characterized by single-crystal X-ray diffractometry and spectrometry. Both iron(Ⅲ) atoms of the binuclear unit are bridged by one oxy atom and two acetate groups. Each iron atom is also bound to facially-coordinating tridentate IDB ligand with the aliphatic nitrogen donor situated trans to the μ-oxy atom. Each iron(Ⅲ) centers is in a distorted octahedral symmetry. The Raman spectroscopy of the novel complexes have been studied and some peak have been attributed.更多还原