节点文献
脱氢枞胺键合交联聚苯乙烯树脂的制备
Preparation and Characterization of Covalently Bonded Dehydroabietylamine Derivatized Cross-linked Polystyrene
【摘要】 运用高分子反应法 ,制备脱氢枞胺键合交联聚苯乙烯树脂。反应分三步进行 :醚化反应、双键环氧化和脱氢枞胺与环氧基开环反应。探讨了每一步合成的最佳工艺条件。通过红外光谱对该功能高分子进行了结构表征。并对该合成产物进行对映体分离的初步应用
【Abstract】 To produce covalently bonded dehydroabietylamine derivatized cross linked polystyrene by macromolecular reaction. The synthetic method involves three steps. The first step is synthesis of ethers and the second step is epoxidation of double bonds. The third step is reaction of dehydroabietylamine with epoxy group. The optimum technological conditions of each step were discussed. The functional macromolecular were characterized by IR. And the product was tried to resolute enantiomers.
【关键词】 脱氢枞胺;
交联聚苯乙烯树脂;
手性固定相;
醚化;
环氧化;
【Key words】 dehydroabietylamine; cross linked polystyrene; chiral stationary phase; synthesis of ethers; epoxidation;
【Key words】 dehydroabietylamine; cross linked polystyrene; chiral stationary phase; synthesis of ethers; epoxidation;
- 【文献出处】 功能高分子学报 ,Journal of Functional Polymers , 编辑部邮箱 ,2001年03期
- 【分类号】O632
- 【被引频次】4
- 【下载频次】114