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EPDM/PA高性能弹性体的某些性能研究

THE STUDY ON SOME PROPERTIES OF SUPER ELASTORMER EPDM/PA

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【作者】 马军冯予星邓自军张立群朱玉俊

【Author】 MA Jun 1, FENG Yu xin 2, DENG Zi jun 2, ZHANG Li qun 2, ZHU Yu jun 2 ( 1Chemical Institute, Chinese Academy of Science, Beijing 100080, China; 2College of Materials Science and Engineering, Beijing University of Chemical Techn

【机构】 中国科学院化学研究所!北京100080北京化工大学材料与科学工程学院!北京100029

【摘要】 研究了 EPDM/ PA共混物的流变性能、耐油性、耐化学溶剂性、吸水性及动态生热。结果表明 ,随 PA用量增多 ,共混物的假塑性变得不明显 ,呈现出宾汉流体的行为 ;共混物的表观粘度随剪切速率的增加而降低 ,表现出假塑性 ;PA分散于基体 EPDM中 ,大幅度提高了基体的耐油性 ;虽然 PA难溶于二甲苯 ,但共混物中的 PA易于被二甲苯刻蚀 ;尽管共混物含 30份的 PA,但仍具有优良的耐吸水性 ;与近似硬度的 EPDM过氧化物硫化胶相比 ,共混物的生热有大幅度降低

【Abstract】 The rheological property, oil reststant property, solvent resistant property, water resistant property, and dynamic heat build up of EPDM/PA compound were reviewed. The result shows that, with the increase of PA amount, pseudoplastic flow becomes unapparent and Binham flow becomes apparent. With the increase of sheartng rate, apparent viscosity of EPDM/PA blending system is decreased and pseudoplastic flow becomes apparent. That PA is dispersed in EPDM improved significantly oil resistant property of EPDM. PA, which is difficuit to be solved by toluene, is easy to be solved by toluene while dispersed in EPDM. EPDM/PA blend, including 30 phr PA, gained excellent water resistant property. Compared with EPDM without PA, the dynamic heat butld up of EPDM/PA blend whose shore A is almost the same as that of the former EPDM is very low.

【基金】 国家九五攻关项目
  • 【文献出处】 高分子材料科学与工程 ,Polymeric Materials Science & Cngineering , 编辑部邮箱 ,2001年03期
  • 【分类号】TQ334
  • 【被引频次】6
  • 【下载频次】162
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