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Ind2Zr(OC6H4Me-p)2和EtnAlCl3-n催化乙烯齐聚的研究

Ethylene Oligomerization Catalyzed by Ind2Zr(OC6H4-p-Me)2/EtnAlCl3-n

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【作者】 钱明星周斌何仁王梅黄勇王辉

【Author】 QIAN Ming Xing, ZHOU Bin, HE Ren *, WANG Mei, HUANG Yong, WANG Hui (State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 116012, China)

【机构】 大连理工大学精细化工国家重点实验室大连理工大学精细化工国家重点实验室 大连116012大连116012大连11

【Abstract】 The catalytic activities and selectivities of Ind 2Zr(OC 6H 4 p Me) 2 and Et n AlCl 3- n ( n =2, A; n =1.5, B; n =1, C) as co catalyst three binary catalyst systems on ethylene oligomerization have been studied at different reaction temperatures, aging temperatures and various reaction time. Under the same reaction condition the catalytic activities of three systems are in the following order: A>B>C. Under optimal reaction conditions, the activity of Ind 2Zr(OC 6H 4 p Me) 2/A is 1 666 g/(g Zr· h) , the selectivity of C 4-10 olefins is 92.7% and the selectivity of α C 4-10 linear olefins is 86.0 %.

【关键词】 乙烯齐聚Ziegler-Natta催化剂α烯烃
【Key words】 EthyleneOligomerizationZiegler Natta catalystα Olefin
【基金】 国家自然科学基金 (批准号 :2 97730 0 8);大连理工大学教育部碳资源综合利用开放实验室 (批准号 :970 0 7K)资助
  • 【文献出处】 高等学校化学学报 ,Chemical Research In Chinese Universities , 编辑部邮箱 ,2001年10期
  • 【分类号】O631.5
  • 【被引频次】10
  • 【下载频次】65
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