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新型化合物[（2,2-bipy）₂（VO₂）₂（HPO₄）]·H₂O晶体的水热合成与表征

Hydrothermal synthesis and characterization of a novel compound [（2,2-bipy）₂（VO₂）₂（HPO₄）]·H₂O

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【Author】 LUAN Guo you 1, WANG Ming hui 2, WANG En bo 1, HAN Zheng bo 1, HU Chang wen 1 (1 Faculty of Chemistry, Northeast Normal University, Changchun 130024, China; 2.Faculty of Resource and Environment Science, Jilin Agriculture University, Changchu

【机构】东北师范大学化学学院!吉林长春130024吉林农业大学资源与环境学院；吉林长春130118；吉林农业大学资源与环境学院!吉林长春130118；东北师范大学化学学院!吉林长春130024；

【摘要】首次通过水热方法合成了新型化合物 [(2 ,2 -bipy) 2 (VO2 ) 2(HPO4) ]·H2 O ,并且通过元素分析 ,IR光谱和X衍射进行了结构表征 .晶体学数据如下 :该晶体为单斜晶系 ,P2 1/n空间群 ,a =0 .92 1 6(2 )nm ,b =1 .61 77(3 )nm ,c=1 .53 2 1 (3 )nm ,V =2 .2 543 (8)nm3,β=99.2 8(2 )°,Z =4 ,Dc=1 74 5kg/m3,F(0 0 0 ) =1 2 0 0 ,R =0 .0 3 65,wR2 =0 .0 82 7.更多还原

【Abstract】 A novel compound, [(2,2-bipy) 2(VO 2) 2(HPO 4)]·H 2O was first prepared by hydrothermal synthesis and characterized by elemental analysis, IR, and single crystal X-ray diffraction. Crystal data:monoclinic, space group P2 1/n,a =0.921 6(2) nm, b = 1.617 7(3)nm , c =1.532 1(3)nm, V =2.254 3(8)nm 3, β =99.28(2)°, Z =4, D c=1 745 kg/m 3, F (000) = 1 200 , R =0.036 5, wR 2=0.082 7.更多还原