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四磺基铝酞菁-阳离子表面活性剂体系应用于白酒中乙醇含量的测定

Tetrasubstituted Sulphonated Aluminum Phthalocyanine-Cationic Surfactant System for Fluorimetric Determination of Ethanol in Alcoholic Beverage

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【作者】 詹心琪李东辉朱庆枝郑洪许金钩

【Author】 Zhan Xinqi (Department of Chemistry, Zhangzhou Teachers’ College, Zhangzhou 363000) Li Donghui, Zhu Qingzhi, Zheng Hong, xu Jingou (The Key Laboratory of Analytical Science of Ministry of Education, Department of Chemistry, Xiamen University, Xiamen 36100

【机构】 漳州师范学院化学系!漳州363000厦门大学化学系分析科学教育部重点实验室!厦门361005

【摘要】 基于四磺基铝酞菁(AlS4 Pc)在阳离子表面活性剂存在下发生诱导缔合而导致体系荧光猝灭,而在乙醇存在下AlS4 Pc解聚而使体系荧光恢复的原理,建立了测定白酒中乙醇含量的新方法。方法的线性区间为0.5%~90%(V/V)乙醇,检测限为0.48%(V/V)。本法已应用于实际酒样中乙醇的直接测定,结果满意。

【Abstract】 A new fluorimetric method was developed for the determination of ethanol in alcoholic beverage. The method is based on the principle that tetrasubstituted sulphonated aluminum phthalocyanine (AlS4Pc), a red-region fluorescent reagent, is induced to associate in the presence of cationic surfactant, cetyltrimehtylammonium bromide (CTMAB), thus its fluorescence is quenched, and then the aggregate is disaggregated by the addition of ethanol and the fluorescence is recovered. This method has a linear determination range of 0. 5% - 90. 0% (V/V), the detection limit is 0. 48% (V/V). The method has been used to determine real alcoholic beverage samples with satisfactory results.

【基金】 国家自然科学基金资助课题(No.29775021)
  • 【文献出处】 分析化学 ,Chinese Journal of Analytieal Chemistry , 编辑部邮箱 ,2001年06期
  • 【分类号】O657.3
  • 【被引频次】20
  • 【下载频次】209
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