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电感耦合等离子体质谱法测定地质样品中铂、钯、钌、铑、铱和金
Determination of Pt, Pd, Ru, Rh, Ir and Au in Geological Samples By Double Focusing High Resolution Inductively Coupled Plasma Mass Spectrometry
【摘要】 研究Te共沉淀分离富集、ICP-MS铂族元素和金测定方法。方法检出限 1~9 pg/g;回收率≥90%。国标GBW07288-GBW07294、加拿大WGB1及南非铂矿SARM7等标样分析表明:结果满意,方法可靠。
【Abstract】 A method for the determination of Pt.Pd. Ru. Rh. Ir and Au in geological samples was studied. The sample was fused by sodium peroxide and determined by a double focusing high resolution inductively coupled plasma mass spectrometer "ELEMENT" after the separation and enrichment by co-precipitation with Te. Detection limit of the method was between 1 -9ng/g and the recovery was > 90%. Our analytical results for some domestic or international reference materials were in agreement with the certified values.
【关键词】 铂族元素;
共沉淀;
地质样品;
等离子质谱分析;
【Key words】 Platinum group element; co-precipitation; geological samples; inductively coupled plasma mass spectrometry;
【Key words】 Platinum group element; co-precipitation; geological samples; inductively coupled plasma mass spectrometry;
- 【文献出处】 分析化学 ,Chinese Journal of Analytieal Chemistry , 编辑部邮箱 ,2001年06期
- 【分类号】O657.63
- 【被引频次】71
- 【下载频次】605