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耐候钢表面稳定锈层形成机理的研究

FORMATION MECHANISM OF PROTECTIVE RUST ON WEATHERING STEEL

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【作者】 张全成吴建生郑文龙王建军陈家光杨晓芳李爱柏

【Author】 ZHANG Quancheng 1,WU Jiansheng 1,ZHENG Wenlong 2, WANG Jianjun 2,CHEN Jiaguang 3,YANG Xiaofang 3,LI Aibai 3 (1 Material Science Department of Shanghai Jiaotong University,Shanghai 200030) (2 Shanghai Material Science Institute,Shanghai 200437)

【机构】 上海交通大学材料科学与工程学院!上海200030上海材料研究所!上海200437宝山钢铁有限公司钢铁研究院!上海200941

【摘要】 研究了耐候钢在青岛近海大气中曝晒 3a的腐蚀行为 ,观察测定了锈层与基体的界面形貌、相组成及锈层中合金元素的分布 .结果表明 ,腐蚀 3a的耐候钢表面锈层有明显的分层现象 ;内锈层组织致密 ,主要有各向同性的α-FeOOH构成 ,在偏光下检测消光 ;外锈层有γ—FeOOH和Fe2 O3 构成 ,在偏光下检测炫光 ;在内锈层中有合金元素的富集

【Abstract】 Corrosion rate of carbon steel and the weathering steel in the marine atmosphere by Qingdao for 3 years was compared,and the distribution of the alloy elements in the rust layer was determined. The result shows that the structure of corrosion rust of weathering steel exposed for 3 years consisted of inner layer and outer layer obviously. The former was compacted and composed of α-FeOOH mainly, and looked dark by the polarized light. However, the latter is of γ-FeOOH and a little FeO, and appeared bright by the polarized light.

  • 【文献出处】 腐蚀科学与防护技术 ,Corrsion Science and Technology Protection , 编辑部邮箱 ,2001年03期
  • 【分类号】TG172.4
  • 【被引频次】109
  • 【下载频次】813
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