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含磷C₆₀衍生物的电化学性能研究

Studies on the Electrochemical Properties of Phosphate Derivatives of C₆₀

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【Author】 LIU Ying 1,DING Li 1,FAN Lou_zhen 1* ,CHENG Fu_yong 2,WU Zhong_da 1 (1.Department of Chemistry,Beijing Normal University,Beijing,100875,China; 2.Research Center of Materials Science,Beijing Institute of Technology,Beijing,100081,China)

【机构】北京师范大学化学系!北京100875；北京理工大学材料科学研究中心!北京100081；

【摘要】利用循环伏安法测试了 3种新合成的C60 膦酸酯衍生物的电化学性能 .通过比较不同取代基的C60 衍生物的电化学性能 ,研究引入基团的结构特性与其得电子能力之间的关系更多还原

【Abstract】 The phosphorus chemistry of fullerene was investigated for the first time. We have synthesised three novel phosphate derivatives of C 60 .Their electrochemical properties were detected by cyclic voltammetry (CV).The influence of different substituents on the electron_accepting ability of methanofullerenes was also observed by the comparative study on the electrochemical properties of different C 60 derivertives.更多还原