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电化学表面处理对SiC纤维的强化作用

REINFORCEMENT MECHANISM OF CVD SiC FIBER BY SiO2 SURFACE FILM

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【作者】 罗鲲石南林祖亚培段亚丁文钟晟

【Author】 LUO Kun, SHI Nanlin, ZU Yapei, DUAN Yading, WEN Zhongsheng (Institute of Metal Research, The Chinese Academy of Sciences, Shenyang 110015)

【机构】 中国科学院金属研究所

【摘要】 采用SEM分析了用电化学表面处理方法得到的高强度SiC纤维表面形貌和断口的结构 讨 论了表面氧化股的形成对用 CVD法制备的 SiC纤维力学性能的影响

【Abstract】 Morphology of the surface and fracture of the high-tensile-strength SiC fiber after electrochemical treatment was analyzed in this paper. During the process of anodic oxidation, SiO2 particles formed in some active regions on the SiC fiber surface at first. then connected together becoming a compact surface layer. Formation of the SiO2 layer smoothened the surface morphology, and lessened the number of surface defects, and also alleviated the locally concentrating of tension. On the other hand. the surface took on compression instead of the inherent slight tension after electrochemical treatment by the differential on Mole volume between SiO2 and SiC, and the occurring and enlarging of the micro-cracks on the surface were seriously restrained. According to the comparison between the measuring values and the calculating results, it is greatly possible that compression is the main reason for the reinforcement of SiC fibers.

【关键词】 SiC纤维表面氧化膜强化作用
【Key words】 SiC fiberSiO2 surface filmreinforcement mechanism
【基金】 八六三计划新材料领域资助项目!863—715—011—0130
  • 【文献出处】 材料研究学报 ,Chinese Journal of Material Research , 编辑部邮箱 ,2001年01期
  • 【分类号】TB383
  • 【被引频次】6
  • 【下载频次】132
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