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铜钴尖晶石复合氧化物的组成对二甲苯完全氧化反应活性的影响

Effect of Composition of Copper-Cobalt Spinel Composite Oxide on Its Catalytic Activity for Xylene Complete Oxidation

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【作者】 付冬胡瑞生阿山沈岳年

【Author】 FU Dong, HU Ruisheng *, A Shan, SHEN Yuenian(College of Chemistry and Chemical Engineering, Inner Mongolia University, Huhhot 010021, China)

【机构】 内蒙古大学化学化工学院内蒙古大学化学化工学院 呼和浩特010021呼和浩特010021呼和浩特010021

【Abstract】 A series of copper cobalt composite oxides with different composition were synthesized by solid phase reaction using citric acid as a complex agent, and characterized with XRD, BET and TPR. The effects of the copper/cobalt ratio on the crystal structure, specific surface area, reduction performance and catalytic activity of the catalyst for xylene combustion were studied. It was found that the catalytic activity of the catalyst has close relation with the copper/cobalt ratio. The interaction between copper and cobalt improved the specific surface area and reduction properties of the samples. The catalyst sample with n (Cu)/ n (Co)=1 has the largest specific surface area, the highest activity and the lowest reduction temperature. At the same time, the experimental results indicated that the spinel CuCo 2O 4 has high catalytic activity for xylene complete oxidation. The addition of opportune copper oxide promotes the CuCo 2O 4 dispersion on the composite oxide.

【基金】 国家自然科学基金 ( 2 986 90 0 1);内蒙古自然科学基金资助项目
  • 【文献出处】 催化学报 ,Chinese Journal of Catalysis , 编辑部邮箱 ,2001年06期
  • 【分类号】O643.3
  • 【被引频次】27
  • 【下载频次】275
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