【摘要】 合成了 6个模型化合物并用以探讨PSⅡ的放氧复合物 (OEC)中Mn簇的结构特征。模型物包含Mn2 (μ_O) 2和 μ_O_μ_羧桥联的二锰结构单元 ,这些单元中的Mn—Mn、Mn……Mn和Mn—O(N)结构参数与PSⅡ系统OEC的相应数据一致 ,暗示OEC中Mn簇可能具有类似的结构特点。还有两个模型物包含了卤素阴离子 ,它们被用于讨论PSⅡ中Cl-与Mn的联系。讨论认为 ,在 5个PSⅡ的S态中 ,具有高价锰中心的S态较之其他S态更有可能因为配体交换而导致Cl-与Mn的配位。更多还原

【Abstract】 Six model compounds have been synthesized and used for probing the structural features of the Mn cluster in oxygen_evolving complex (OEC) of photosystem Ⅱ (PSⅡ). The model compounds contain Mn 2(μ_O) 2 and μ_O_μ_carboxylato di_manganese structural units, which offer Mn—Mn, Mn……Mn, and Mn—O(N) structural parameters consistent with the corresponding data of the OEC in PSⅡ, implying that the Mn cluster in OEC may possess similar structural features. Two model compounds containing halide anion have been used for discussing the binding of Cl - to Mn in PSⅡ. It is suggested that in the five S states, ligand exchange would lead to the ligation of chloride to Mn in the S states with Mn of higher valence.更多还原