【摘要】 手性双膦配体 2 ,2′-双 (二苯基膦基 ) - 1,1′-联萘与钌、铑离子形成的配合物可作为高效均相催化剂 ,用于烯烃和羰基的高对映选择性氢化 ,或烯烃的对映选择性异构化。本文对此领域的研究状况进行简介。更多还原

【Abstract】 The complex formed by chiral bisphosphine chelate 2,2′ bis (diphenylphosphino) 1,1′ binaphthyl and Ru or Rh ion can be used to catalyzed the homogeneous asymmetric hydrogenation of carbonyl and alkene compounds, as well as the enantioselective isomerization of alkene.更多还原