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气溶胶和餐厅烟尘中有机氯农药特征与来源

Characteristic and sources of organochlorine pesticides from cooking smoke and aerosols.

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【作者】 成玉盛国英邵波林峥闵育顺傅家谟

【Author】 CHENG Yu;SHAO Bo( State Key Laboratory of Estuarine and Coastal Research, East China Normal University,Shanghai 200062,China) SHENG Guo-ying; LIN Zheng; MIN Yu-shun; FU Jia-mo(State Key Laboratory of Organic Geochemistry, Guangzhou Institute of Geochemi

【机构】 华东师范大学河口海岸国家重点实验室!上海200062中国科学院广州地球化学研究所有机地球化学国家重点实验室!广东广州510640中国科学院广州地球化学?

【摘要】 使用GCIECD(气相色谱/电子捕获检测器)及毛细色谱柱定量分析粤港地区气溶胶和餐厅烟尘中有机氯农药的组成和分布特征,并分析其主要来源研究表明,从研究区大气环境中的气溶胶样品及餐厅烟尘颗粒物中,检出12种有机氯农药.其中6种DDT(滴滴涕)及其代谢物,3种BHC(六六六)和其它3种含氯农药,浓度范围在0.20~60、78pg/m3.靠近农田和果园的气溶胶及餐厅烟尘颗粒物中4,4’-DDT和2,4’-DDT浓度较高,说明大气环境中的DDT不仅来源于农药施撒过程和农田表层土壤,而且还来源于动物脂肪高温裂解的释放。

【Abstract】 The compositions and concentrations of organochlorine Pesticides from cooking smoke and aerosols of southern Guangdong and Hong Kong are analyzed with GC/ECD (gas chromatograph/electron capture detector) and capillny chromatograph. The distribution and sources of organochlorine peshcides are also studied. The result shows that 12 kinds of organochlorine pesticides, including 6 kinds of DDT and its metabolites, 3 kinds of BHCs and 3 kinds of chlorine’ containing pesticides, with concentrations from 0.20 to 60.78 pglm3, are detected in the cooking smoke and aerosols in the study area. The aerosols collected near farmland or orchard or cooking smoke contain much higher concentraetions of 4,4’-DDT and 2,4’-DDT, which indicates that DDT and its metabolites in atmosphere environment not only come from the process of spreading pesticides or from the polluted surface soil, but also from the release of pyrogenic degradation of animal fat.

【基金】 有机地球化学国家重点实验室开放基金!OGL-9604;中国博士后基金
  • 【文献出处】 中国环境科学 ,CHINA ENVIRONMENTAL SCIENCE , 编辑部邮箱 ,2000年01期
  • 【分类号】X132
  • 【被引频次】22
  • 【下载频次】192
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