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316L不锈钢微动磨蚀过程表面钝化膜自修复行为研究

REPASSIVATION BEHAVIOR of 316L STAINLESS STEEL IN FRETTING WEAR AND CORROSION PROCESS

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【作者】 闫建中吴荫顺李久青张琳

【Author】 YAN Jianzhong; WU Yinshun; LI Jiuqing; ZHANG Lin (Corrosion and Protection center, Open Laboratory of Corrosion, Erosion and Surface Technology, University of Science and Technology Beijing, Beijing 100083)

【机构】 北京科技大学腐蚀与防护中心腐蚀、磨蚀与表面技术开放研究实验室!北京100083北京科技大学腐蚀与防护中心腐蚀、磨蚀与?

【摘要】 采用球-平面接触设备,对轧制固溶316L不锈钢在不同NaCl溶液微动过程中,表面钝化膜的自修复行为进行了研究,讨论了溶液腐蚀特性及缝隙腐蚀行为对微动过程的影响.结果表明,溶液腐蚀特性的改变引起材料钝化膜自修复行为的差异,但不显著.在去离子水溶液中,316L不锈钢表面钝化膜保持了较高的自修复能力,稳定阶段表面钝化膜自修复约占平衡态下钝化膜厚度的 17%,说明316L不锈钢表面钝化膜在微动过程并不能长期有效地保护材料免受腐蚀损伤.

【Abstract】 Repassivation behavior of 316L stainless steel in fretting has been studied in different NaCl solutions. And the effect of crevice corrosion occurring during fretting process had been discussed. The results showed that different solutions resulted in different repassivation behavior. But the difference of repassivation behaviors in different solutions was not remarkable: in pH10. 0 (0. 9 % NaCl) solution, repassivating process could last for about 5 x 104 cycles; while fretting in other corrosive solutions, no more repassivation process took place after 4 x 104 cycles. When fretting was carried out in deionized water the material had better repassivation ability. The growing film might take up 17 percent of passive film in static condition. The evidence suggested that passive film could not protect the material from corrosion damage effectively in fretting.

【基金】 高等学校博士点基金项目!(97000812)
  • 【文献出处】 中国腐蚀与防护学报 ,Journal of Chinese Society For Corrosion and Protection , 编辑部邮箱 ,2000年06期
  • 【分类号】TG17
  • 【被引频次】52
  • 【下载频次】404
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