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4,4’-二硝基二苯乙烷(烯)的合成
Synthesis of 4,4’-Dinitrodibenzyl and 4,4’-Dinitrostilbene
【Abstract】 The title compounds were synthesized by oxidative dimerization of p-nitrotoluene. The effects of solvents, bases and oxidizing agents on the dimerization were investigated. The results showed that by selecting appropriate solvents, oxidizing agents, base catalysts and controlling technical conditions the yields of dinitrodibenzyl and dinitrostilbene could be reached 89.4% and 74.6%, respectively.
【关键词】 二硝基二苯乙烷;
二硝基二苯乙烯;
合成;
硝基甲苯;
氧化二聚反应;
【Key words】 dinitrobenzyl; dinitrostilbene; synthesis; nitrotoluene; oxidative dimerization8;
【Key words】 dinitrobenzyl; dinitrostilbene; synthesis; nitrotoluene; oxidative dimerization8;
【基金】 天津市 2 1世纪青年科学基金资助项目!(97370 16 11)
- 【文献出处】 应用化学 ,Chinese Journal of Applied Chemistry , 编辑部邮箱 ,2000年06期
- 【分类号】O625.1
- 【被引频次】5
- 【下载频次】167