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掺杂聚丙炔醇及其酯的湿敏特性

Humidity Sensing Characteristics of Doped Poly(propargyl alcohol) and Poly(propargyl acetate)

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【作者】 孙宏枚杨慕杰凌明芳

【Author】 SUN Hong Mei * (Department of Chemistry and Chemical Engineering,Suzhou University,Suzhou 215006) YANG Mu Jie (Department of Polymer Science and Engineering,Zhejiang University,Hanzhou) LING Ming Fang (Department of Information and Electr

【机构】 苏州大学化学化工系!苏州215006浙江大学高分子科学与工程系!杭州浙江大学信息与电子学系!杭州

【Abstract】 Poly(propargyl alcohol)(POHP) and poly(propargyl acetate)(PPAT) were prepared by using palladium acetylide catalysts [Pd(C CCH 2OR) 2(PPh 3) 2] (R=H,OC 2H 5) and doped with FeCl 3 or H 2SO 4 as humidity sensing materials. The doped polymers were found to have good humidity sensitivity as the impedance variation covered about two orders of magnitute (10 4~10 6 Ω) at RH% ranged from 11% to 96%. The effects of polymer structures on the humidity sensing behavior were compared.

【基金】 国家自然科学基金!资助项目 (2 95 74177)
  • 【文献出处】 应用化学 ,CHINESE JOURNAL OF APPLIED CHEMISTRY , 编辑部邮箱 ,2000年04期
  • 【分类号】O632
  • 【被引频次】3
  • 【下载频次】58
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