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掺杂聚丙炔醇及其酯的湿敏特性
Humidity Sensing Characteristics of Doped Poly(propargyl alcohol) and Poly(propargyl acetate)
【Abstract】 Poly(propargyl alcohol)(POHP) and poly(propargyl acetate)(PPAT) were prepared by using palladium acetylide catalysts [Pd(C CCH 2OR) 2(PPh 3) 2] (R=H,OC 2H 5) and doped with FeCl 3 or H 2SO 4 as humidity sensing materials. The doped polymers were found to have good humidity sensitivity as the impedance variation covered about two orders of magnitute (10 4~10 6 Ω) at RH% ranged from 11% to 96%. The effects of polymer structures on the humidity sensing behavior were compared.
【关键词】 聚丙炔醇;
聚醋酸丙炔酯;
掺杂;
湿敏性;
【Key words】 poly(propargyl alcohol); poly(proargyl acetate); doping; humidity sensing property;
【Key words】 poly(propargyl alcohol); poly(proargyl acetate); doping; humidity sensing property;
【基金】 国家自然科学基金!资助项目 (2 95 74177)
- 【文献出处】 应用化学 ,CHINESE JOURNAL OF APPLIED CHEMISTRY , 编辑部邮箱 ,2000年04期
- 【分类号】O632
- 【被引频次】3
- 【下载频次】58