【摘要】 研究了琥珀酸二 (2 -乙基己基 )酯磺酸钠 (AOT)与聚合物表面活性剂混合后在非极性溶剂中的聚集行为 .结果表明 ,随聚合物与 AOT摩尔比的增大 ,体系的 CMC逐渐增大 ,但该摩尔比大于 1∶ 1时 ,用水增溶法不能测出 CMC;研究了荧光探针 Ru(bpy) 2 + 3在该混合反胶团中的荧光行为 .随有机相含水量 W0 增大 ,对微极性敏感的荧光探针的最大发射波长 λmax逐渐红移 ,荧光强度 F则逐渐减弱 .随聚合物含量增大 ,混合体系表面活性剂极性基的水合过程在较小 W0 下完成更多还原

【Abstract】 The aggregation behavior of AOT(bis(2 ethylhexyl) sodium sulfosuccinate) mixed with polymer surfactants GP330(glycerin polyoxypropyl ether) or L61(poly(PEO b PPO) in nonpolar solvents and the luminescence behavior of ruthenium tris(2,2 bipyridine) in the mixed reverse micelles have been studied. The results indicated that CMC of the system increased with increase in mole ratio of the polymer to AOT, but it couldnt be measured by the water solubilization method when the mole ratio increased to 1∶1, and that the fluorescence intensity of the probe decreased with increase in water content in the reverse micelles and the emission λ max shifted to longer wavelengths. The results also indicated that increase in content of polymer surfactants could cause the hydration to be completed in lower W 0(mole ratio of H 2O to surfactant in organic phase) value.更多还原