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硫酸铵存在下碘化钾-乙醇体系萃取分离镉

Extraction Separation of Cadmium by KI-Ethanol in the Presence of (NH42SO4

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【作者】 李全民耿新华刘奇张青芬

【Author】 LI Quan Min *, GENG Xin Hua, LIU Qi, ZHANG Qing Fen(Department of Chemistry,He′nan Normal University,Xinxiang 453002)

【机构】 河南师范大学化学与环境科学学院!新乡453002

【Abstract】 A study on liquid liquid extraction of cadmium based on KI ethanol in the presence of ammonium sulphate has been performed. It shows that the charged complex compound CdI 2- 4 could be easily extracted into the ethanol phase. Common ions such as Fe 3+ , Co 2+ , Ni 2+ , Mn 2+ , Zn 2+ , Al 3+ and Cr 3+ would not be extracted into the ethanol phase and Cd 2+ could be separated completely from them by mixture of 3.0 g (NH 4) 2SO 4 and 0.2 g KI in 10.0 mL 30%(volume fraction) ethanol solution at pH=1~5.

【关键词】 萃取分离乙醇碘化钾
【Key words】 cadmiumextraction separationethanolpotassium iodide
【基金】 河南省科委、省教委自然科学基金
  • 【文献出处】 应用化学 ,CHINESE JOURNAL OF APPLIED CHEMISTRY , 编辑部邮箱 ,2000年01期
  • 【分类号】X132
  • 【被引频次】45
  • 【下载频次】130
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