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柠檬酸络合法合成锂离子电池正极材料Li1+xMn2O4

Preparation of Li1+xMn2O4 for Lithium ion Battery by Citric Acid Complexation Method

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【作者】 刘培松刘兴泉陈召勇于作龙张伯兰

【Author】 LIU Pei Song, LIU Xing Quan, CHEN Zhao Yong, YU Zuo Long, ZHANG Bai Lan * (Research and Developing Center of Functional Materials,Chengdu Institute of Organic Chemistry,Chinese Academy of Sciences,Chengdu 610041)

【机构】 中国科学院成都有机化学研究所功能材料研究开发中心!成都610041中国科学院成都?

【Abstract】 The cathode material Li 1+ x Mn 2O 4 was prepared by a modified citric acid complexation method. The influences of temperature, sintering time and n (Li)/ n (Mn) ratio on the structure of the products have been explored, characterized and tested by XRD, TEM, BET measurements. The sample sintered at 750 ℃ for 12 h had greater charge/discharge capacity, better cyclic stability under electric current charge/discharge cycle. The initial capacity reached 120 mA·h/g with the charge/discharge efficieney of 98% and maintained 115 mA·h/g after 50 cycles.Preparation

【基金】 国家科委和四川省科委资助!项目 ( 98 D 1 0 2 )
  • 【文献出处】 应用化学 ,CHINESE JOURNAL OF APPLIED CHEMISTRY , 编辑部邮箱 ,2000年01期
  • 【分类号】TM241
  • 【被引频次】36
  • 【下载频次】197
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