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柠檬酸络合法合成锂离子电池正极材料Li1+xMn2O4
Preparation of Li1+xMn2O4 for Lithium ion Battery by Citric Acid Complexation Method
【Abstract】 The cathode material Li 1+ x Mn 2O 4 was prepared by a modified citric acid complexation method. The influences of temperature, sintering time and n (Li)/ n (Mn) ratio on the structure of the products have been explored, characterized and tested by XRD, TEM, BET measurements. The sample sintered at 750 ℃ for 12 h had greater charge/discharge capacity, better cyclic stability under electric current charge/discharge cycle. The initial capacity reached 120 mA·h/g with the charge/discharge efficieney of 98% and maintained 115 mA·h/g after 50 cycles.Preparation
【关键词】 Li1+xMn2O4;
合成;
柠檬酸络合法;
锂离子电池;
【Key words】 Li 1+ x Mn 2O 4; preparation; citric acid complexation; Li ion battery;
【Key words】 Li 1+ x Mn 2O 4; preparation; citric acid complexation; Li ion battery;
【基金】 国家科委和四川省科委资助!项目 ( 98 D 1 0 2 )
- 【文献出处】 应用化学 ,CHINESE JOURNAL OF APPLIED CHEMISTRY , 编辑部邮箱 ,2000年01期
- 【分类号】TM241
- 【被引频次】36
- 【下载频次】197