【摘要】 综述了近 10多年来国内外非卟啉、希夫碱类含氮、磷、砷、锑杂原子配体的钌配合物催化烃类氧化反应的研究进展。详细描述了不同氧化剂 (O2 ,TBHP ,KHSO5,PhIO)下烃类氧化反应的机理以及不同的烯烃及烷烃在一定反应条件下的反应活性。更多还原

【Abstract】 This paper reviewed the advance of some hydrocarbons oxidation catalyzed by Ru-complixes containing nitrogen,phosphorus,arsenic,stibium ligands non-Porphyrins or Schiff Bases.The mechanism in the oxidation by different oxidants(O 2,TBHP,KHSO 5,PhIO)and reaction activity for alkene or alkane under specific reaction condition had been described in detail.更多还原