【摘要】 报道了1-甲基-1-乙基-3-丁烯基环戊二烯基稀土二氯化物的合成。用元素分析、质谱、红外光谱和核磁共振表征了这类配合物的组成为[C₅H₄C（CH₃）（C₂H₅）CH₂CH=CH₂]LnCl₂·MgCl₂·THF[Ln=La（1）,Nd（2）,Sm（3）,Gd（4）]。更多还原

【Abstract】 The trichlorides of lanthanum, neodymium, samarium and gadolinium reacted with an equivalent [C5H4C(CH3)(C2H5)CH2CH=CH2]MgCl in THF at room temperature for 12 h to give 1 - methyl - 1 - ethyl - 3 -butenyl cyclopentadienyl lanthanide dichloride complexes. Their constitutional formula were characterized by elementary analyses, MS, IR and 1H NMR to be [C5H4C(CH3)(C2H5)CH2CH=CH2]LnCl2·MgCl·THF[Ln = La(1), Nd(2), Sm(3), Gd(4)].更多还原