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有机同系物性质的递变规律研究

Regularity of Physicochemical Properties for Homologous Organic Compounds

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【作者】 聂长明; 范明舫;

【Author】 Nie Chang - Ming , Fan Ming - Fang (Department of Chemical Engineering, Central - South Institute of Technology, 421001 Hengyang)

【机构】 中南工学院化学工程系; 中南工学院化学工程系 衡阳 421001; 衡阳 421001;

【摘要】 以有机同系物结构重复单元数值连续变化为模型,得到同系物性质递变的两个基本规律:P=a+bn和P=c+kln((n+a)/(n+b)),a,b,c人均为常数,n为结构重复单元数值,P为同系物的物性。一般地,加和型性能遵守直线变化规律,而结构型和凝聚型性能遵守同系对数线性规律。

【Abstract】 With the model that the number of repeating units of the homologous series varies successively, two fundamental relationships have been developed:P = a + bn and P = c + kln n+a/n + bwhere a,b,c,k all refer to the constants, n to the number of repeating units, P to the properties for ho-mogolous series. Generally, additive type properties conform to the linear relationship, and the structural - type properties and condened - type properties to the homologous logarithmic linear relationship.

  • 【文献出处】 有机化学 ,Chinese Journal of Organic Chemistry , 编辑部邮箱 ,2000年01期
  • 【分类号】O621
  • 【被引频次】16
  • 【下载频次】138
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