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水热条件下CaO—MgO—SiO2—H2O体系中反应物的竞争与产物的转化机制
COMPETITION MECHANISM OF REACTANT AND TRANSITION MECHANISM OF RESULTANT OF CaO—MgO—SiO2-H2O HYDROTHERMAL SYSTEM
【摘要】 本文研究了 Ca O—Mg O—Si O2 — H2 O体系的水热反应特性。结果表明 :在 Ca O— Mg O—Si O2 一 H2 O系统中 ,Ca O优先与 Si O2 反应生成水化硅酸钙 ,Mg O部分固溶于水化硅酸钙中 ,部分生成 Mg( OH) 2 ,部分与剩余的 Si O2 反应生成水化硅酸镁 ;Mg O固溶时 ,可促进托勃莫来石向硬硅钙石转化 ,不固溶 ,则其转化温度提高
【Abstract】 The reaction characteristics of CaO-MgO-SiO 2-H 2O system under hydrothermal condition were studied. The results show that, in the CaO-MgO-SiO 2-H 2O system, CaO firstly react with SiO 2 to form calcium silicate hydrates whilst, some of the MgO dissolve in the calcium silicate hydrates, some of the MgO form Mg(OH) 2, some of the MgO react with surplus SiO 2 to form magnesium silicate hydrates. The Presence of MgO can promote the change from tobermorite to xonotlite, without MgO, the temperature of the change increases.
【Key words】 CaO-MgO-SiO 2-H 2O system; hydrothermal reaction; thermodynamics; function of competition; function of change;
- 【文献出处】 西南工学院学报 ,Journal of Southwest China Institute of Technology , 编辑部邮箱 ,2000年04期
- 【分类号】O642
- 【被引频次】6
- 【下载频次】313