节点文献
氯化镧与甘氨酸配位反应的热化学研究
Thermochemical Study of the Reaction of Lanthanum Chloride Coordinated with Glycine
【Abstract】 The reaction enthalpy of coordination reaction of lanthanum chloride with Glycine is determined by solution calorimetry in an isoperibel reaction calorimeter. The calormetric solvent is the solution of hydrochloric acid (2 mol· L- 1), a new thermochemical cycle is designed. According to the results, the following date: (298.2 K)=- 4.310 kJ· mol- 1 (La(Gly)3Cl3· 5H2O, s, 298.2 K)=- 4222.93 kJ· mol- 1 were obtained.
【关键词】 热化学;
氯化镧;
甘氨酸;
标准生成焓;
【Key words】 Thermochemistry; Lanthanum chloride; Glycine; Standard enthalpy of format?;
【Key words】 Thermochemistry; Lanthanum chloride; Glycine; Standard enthalpy of format?;
【基金】 国家自然科学基金!(29773033);湖北省教育委员会科学研究计划资助项目!( 99CO44)
- 【文献出处】 物理化学学报 ,Acta Physico-chimica Sinica , 编辑部邮箱 ,2000年12期
- 【分类号】O642
- 【被引频次】7
- 【下载频次】72