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钡对氧化铝的高温热稳定作用

Thermal Stabilization of Barium on the Alumina at High Temperature

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【作者】 刘勇王敬先杨竹仙何阿弟陈晓银

【Author】 Liu Yong Wang Jingxian Yang Zhuxian He Adi Chen Xiaoyin(Department of Environmental Science and Engineering, Fudan University,Shanghai 200433)

【机构】 复旦大学环境科学与工程系!上海200433

【Abstract】 The thermal stabilization mechanism of barium and the effects of preparation methods, barium content and calcination temperature were studied by BET specific surface area and powder X ray diffraction. It was found that barium can stabilize the alumina at high temperature (1000 ℃) and the stabilization effect was enhanced with the increase of the barium content, whereas, the overabundance weakened the stabilization effect. The preparation methods influenced the thermal stability of alumina and the stabilization effect of barium. At high temperature, the stabilization effect of barium species can be attributed to the dispersed baria and not hexaaluminate retarding the loss of specific surface area due to the sintering and αphase transformation within the initial 1 h of the calcination process.

【关键词】 氧化铝热稳定性改性
【Key words】 AluminaThermal stabilityBariumModification
【基金】 福特-中国研究与发展基金!(9712303)资助项目
  • 【文献出处】 物理化学学报 ,ACTA PHYSICO-CHIMICA SINICA , 编辑部邮箱 ,2000年06期
  • 【分类号】O614.2
  • 【被引频次】33
  • 【下载频次】195
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