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混合表面活性剂模板法合成立方相介孔含钛氧化硅
Synthesis of Cubic Mesoporous Titanium-containing Silica by Mixed Surfactant Templating
【Abstract】 Cubic mesoporous titaniumcontaining silica(TiMCM48) can be synthesized by using mixed surfactants CTABC nHN 2(n=8,10,12,14) as templates in basic medium.Characterization results obtained from the determination of XRD,TEM and N 2adsorption show that the products possess highquality TiMCM48.The effect of the chain length of the alkylamine and the ratio of titanium to silicium on the structure of the cubic mesophases were investigated.It was revealed that the mesophase transition from cubic to lamellar structure occurred with increasing alkylamine chain length and Ti/Si ratio.
【关键词】 混合表面活性剂;
立方相;
介孔含钛氧化硅;
【Key words】 Mixed surfactant templating; Cubic structure; Mesoporous titanium-containing silica;
【Key words】 Mixed surfactant templating; Cubic structure; Mesoporous titanium-containing silica;
【基金】 国家攀登计划!(97021107);国家自然科学基金重大项目!(299925904)资助
- 【文献出处】 物理化学学报 ,ACTA PHYSICO-CHIMICA SINICA , 编辑部邮箱 ,2000年05期
- 【分类号】TQ424
- 【被引频次】38
- 【下载频次】177