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Na2CrO4-(NH4)2CrO4-H2O体系的相图
Phase Diagram of Na2CrO4- (NH4 )2CrO4-H2O System
【摘要】 铬盐工业是无机盐工业的一个主要分支,其主要产品有重铬酸钠、铬酸酐、铬酸铵、氧化铬等,广泛用于合金材料、电镀、制革、印染、橡胶等部门,是国民经济中重要的基础化工原料工业.铬盐生产系先将铬铁矿制成铬酸钠及重铬酸钠,然后再进一步加工制成其它铬盐产品.在铬盐...
【Abstract】 The phase diagrams of Na2CrO4- (NH4)2CrO4-H2O system at 20℃ and 50℃ have been determined by solubility method. The experimental results have also been verified by mathematical method. The phase diagrams show that there is a double salt of NaNH4Cro4· 2H2O formed in the system, which will decrease the purity of (NH4)2CrO4 Consequently, a method is found to separate the fixture of ammonium chromate and double salt by analysing the phase diagrams.
【关键词】 相图;
分离;
铬酸铵;
复盐;
【Key words】 <Keyworys>Phase diagram; Separation; Ammonium chromate; Double salt;
【Key words】 <Keyworys>Phase diagram; Separation; Ammonium chromate; Double salt;
【基金】 中国科学院“九·五”资源环境特别支持项目!KZ95T.05
- 【文献出处】 物理化学学报 ,ACTA PHYSICO-CHIMICA SINICA , 编辑部邮箱 ,2000年01期
- 【分类号】O642.542
- 【被引频次】2
- 【下载频次】114