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用蒙脱土酸处理法制备洗用4A沸石过程中石英问题的探讨

The Discussing of Quartz Problem in the Synthesis of Detergent-Used Zeolite 4A from Montmorillonite

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【作者】 黄明刘志城董家禄须沁华

【Author】 HUANG Ming, LIU Zhi-Cheng, DONG Jia-Lu ,XU Qin-Hua (Department of Chemistry, Nanjing University,Nanjing 210093)

【机构】 南京大学化学系!南京 210093

【Abstract】 Zeolite 4A is the main substitute builders for sodium tripolyphosphate in non-phosphated detergent. It can be manufactured from savageness clay and the cost may greatly be reduced by this method. In the manufacturing process of detergent-used zeolite 4A from montmorillonite, it is important to remove quartz from clay or zeolite, otherwise the product will not qualified for detergent additive. This article provides two methods, the calibration curve method of quartz content by XRD and the calibration curve method of aluminium ion concentration in synthetic system, to determine the quartz content. Then three methods of removing quartz were studied on, including the methods of whirlwind during the mill run, filtration after alkalinization of silicic acid gel and sedimentation of zeolite.

【基金】 国家863计划项目!(No.715-064-0120)。
  • 【文献出处】 无机化学学报 ,CHINESE JOURNAL OF INORGANIC CHEMISTRY , 编辑部邮箱 ,2000年05期
  • 【分类号】TQ649
  • 【被引频次】17
  • 【下载频次】94
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