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铕(Ⅲ)三元配合物荧光性质的研究

Study on Fluorescent Properties of Europium (Ⅲ) Ternary Complexes

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【作者】 成义祥王昀初陶中东张征林

【Author】 CHENG Yi-Xiang; WANG Yun-Chu; TAO Zhong-Dong; ZHANG Zheng-Lin (Southeast University, Chemistry and Chemical Engineering Department, Nanjing 210096)

【机构】 东南大学化学化工系!南京 210096

【Abstract】 According to fluorescent spectra of a series of Eu(Ⅲ) ternary complexes in the three solvents EtOH, DMF and CH3CN, the fluorescence is stronger in the solvent CH3CN than in the solvents EtOH and DMF, and fluorescent intensity is contrary to the affinity of three solvents with rare earth ions. Center ions emit fluorescence mainly by an intramolecular energy transfer from the broad absorbing β-diketonate TTA, BTA or BA to the chelated rare earth ions.

【关键词】 稀土β-二酮荧光光谱三元配合物
【Key words】 europiumβ-diketoneternary complexfluorescent spectra
【基金】 国家自然科学基金!(No.59582005)
  • 【文献出处】 无机化学学报 ,CHINESE JOURNAL OF INORGANIC CHEMISTRY , 编辑部邮箱 ,2000年03期
  • 【分类号】O614.3
  • 【被引频次】29
  • 【下载频次】176
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