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大气中金属阴极保护用β-Al2O3粉体材料的制备与性质

Preparation and Characteristic of β-Al2O3 Powdered Material as Electrolytic Coating for Cathode Protection in Atmosphere

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【作者】 樊增钊陈昆刚尹耀波徐孝和

【Author】 FAN Zeng-Zhao, CHEN Kun-Gang, YIN Yao-Bo, XU Xiao-He (Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 200050, China)

【机构】 中国科学院上海硅酸盐研究所!上海200050

【摘要】 研究了β-Al粉体材料的制备工艺与性质,这种粉体材料可以采用慢速升温、分 阶段保温的工艺,煅烧LiCO、NaCO和Al的均匀混合物不经球磨直接制得.根据使用要求与生产条件,混合物可用干混、半湿混-过筛或喷雾干燥法来制备.粉体材料主要由β/β-Al组成,β相的相对含量>70%,加入适当的粘结剂与溶剂,可将其制成大气环境 中金属管道外的固体电解质涂层.涂层中粉体的化学与电化学性能稳定,其阴极极化曲线有明显的平坦区,可用于阴极保护技术.

【Abstract】 β-Al2O3 powdered material could be prepared from the mixtures of Li2CO3, Na2CO3 and AL2O3, which were obtained by dry mixing, wet mix-screening or spray-drying process, by stepped calculating without grinding. The effect of preparation condition on the properties of the powdered material was showed. The powder composed of β/β"-Al2O3 in principle, f(β")>70%, could be fabricated into solid electrolytic coating for metal pipeline in atmosphere, with some binders and solvents. The powder in the coating wus stable chemically and electrochemically to metal, binders and moistur. The polarization behavior of cathode for "Beta-coating" showed that there was a flat at the polarization curve, which could be evajuated for the cathode protection of metal in atmosphere.

  • 【文献出处】 无机材料学报 ,JOURNAL OF INORGANIC MATERIALS , 编辑部邮箱 ,2000年04期
  • 【分类号】TF12
  • 【被引频次】5
  • 【下载频次】109
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