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溴酸钾-偶氮胭脂红B体系催化光度法测定痕量亚硝酸根

Catalytic Spectrophotometric Determination of Trace Nitrite Based on Oxidation of Axocarmine B by Potassium Bromate

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【作者】 张爱梅何凤云杜凤香王美玲韩金龙

【Author】 Zhang Aimei 1) He Fengyun 1) Du Fengxiang 1) Wang Meiling 1) HanJinlong 2) ( 1) Department of Chemistry,Liaocheng Teachers University Liaocheng 252059; 2) Liaocheng Business School)

【机构】 聊城师范学院化学系!聊城252059聊城商业学校

【摘要】 基于亚硝酸根在酸性条件下对溴酸钾氧化偶氮胭脂红 B褪色的催化作用 ,建立了灵敏的催化光度测定痕量亚硝酸根的新方法 .测定线性范围为 :0~ 0 .5 ug/ m L,检出限 0 .10 ug/ m L 方法灵敏简便 ,选择性好 ,用于测定水中痕量亚硝酸根 ,结果满意 .

【Abstract】 A new catalytic spectrophotometric method for the determination of trace nitrite was proposed.It is based on the catalyzed discoloring reaction of axocarmine B oxidized by potassium bromate in sulfuric acid medium.The linear range for nitrite is 0~ 0.5 ug/mL.The detection limit is 0.10ug/mL.The method is sensitive,simple with good selectivity.The method has been applied to the determination of trace nitrite in water samples with satisfactory resulte.

  • 【文献出处】 聊城师院学报(自然科学版) ,Journal of Liaocheng Teachers College(Natural Science Edition) , 编辑部邮箱 ,2000年01期
  • 【分类号】O657.3
  • 【被引频次】2
  • 【下载频次】24
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