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金属氧化物负载的KI对合成碳酸丙烯酯的催化性能
Synthesis of Propylene Carbonate Catalyzed by Metal Oxide Supported KI
【摘要】 以金属氧化物负载的碘化钾为催化剂对工氧化碳与环氧丙烷环加成反应进行了研究,考察了反应条件的影响。结果表明,该催化剂是合成碳酸丙烯酯的高效催化剂。基于载体的性质对催化反应机理进行了初步探讨。
【Abstract】 Cycloaddition between propylene oxide and carfor dioxide was invest igated in the presence of metaloxide supported potassiurn iodide. The results show that potassium iodide supported on amphoteric metal oxidesis highly active towards the cycloaddition. Propylene carbote can be efficiently swithesized with KI/ZnO ascatalyst under optimal conditions. Supports play an important promtion role in the cycloaddition.
【关键词】 金属氧化物载体;
碳酸丙烯酯;
催化合成;
【Key words】 metal oxide support; propylene carbonate; catalytic synthesis;
【Key words】 metal oxide support; propylene carbonate; catalytic synthesis;
【基金】 国家自然科学基金;山西省自然科学基金
- 【文献出处】 石油化工 ,PETROCHEMICAL TECHNOLOGY , 编辑部邮箱 ,2000年02期
- 【分类号】O643
- 【被引频次】33
- 【下载频次】284