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水蒸汽存在下异丙苯合成失活FX-01催化剂的烧炭再生
Regeneration under Steam of Coked FX-01 Catalyst Used in Isopropylbenzene Synthesis
【摘要】 以用于异丙苯合成的中试失活FX- 01 催化剂为研究对象,在不同温度下进行烧炭再生,并对再生催化剂的活性、酸性、炭含量、比表面积进行表征和测试,发现失活FX- 01 催化剂在400 ~450 ℃时其活性、酸性及比表面积基本得以恢复。继续升高温度,由于水蒸汽对沸石骨架的脱铝作用,对催化剂的再生将起负面的影响。
【Abstract】 The properties of coked and regenerated FX-01 catalyst by air steam used in the synthesis of isopropylbenzene were investigated by using TPD,TPO and adsorption/desorption methods.The activity,acidity,content of coke and inner surface area are recoverd under 400~450 ℃.Because higher temperature will remove some Al from framework of β zeolite by steam,the temperature of regenerated should not surpass 500 ℃.
- 【文献出处】 石油化工 ,PETROCHEMICAL TECHNOLOGY , 编辑部邮箱 ,2000年01期
- 【分类号】TQ241.14
- 【被引频次】15
- 【下载频次】91