【摘要】 由零场分裂随压力和温度变化的实验数据和晶体结构确定了状态方程 ,并采用完全对角化方法 ,研究了NiSiF6 ·6H2 O的零场分裂随压力和温度的变化行为 .理论结果与实验值符合得很好 .更多还原

【Abstract】 The state etuations are determined from the experimental results on the pressure and temperature dependence of the zero-field splitting and crystal structure.The pressure and temperature dependence of the zero-field splitting of NiSiF 6·6H 2 O have been investigated by adopting the method of complete diagonlization and useing the state equations.The theoretical results agree well with experimental findings.更多还原