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用光散射法测表面活性剂胶束的表观摩尔质量

THE MEASUREMENT OF THE APPARENT MOLAR WEIGHT OF THE MICELLE IN THE SURFACTANT SOLUTION USING LIGHT SCATTER METHOD

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【作者】 张蓉竹杨春林王良兵何玉萼蔡邦维

【Author】 ZHANG Rong zhu 1, YANG Chun lin 1, WANG liang bing 2 HE Yu è 2, CAI Bang wei 1 [WT5”BZ](1.Department of Opto electronics Science and Technology,Sichuan University, Chengdu 610064, China; 2.Department of Chemistry,

【机构】 四川大学光电系!成都610064四川大学化学系!成都610064

【摘要】 介绍了光散射法测量胶束表观摩尔质量的方法 ,以Rayleigh散射公式为理论基础 ,设计并调试了实验装置 ,用CCD摄像机系统对激光通过试液所产生的散射光进行采样 ,并由计算机进行运算处理 ,由此测定了表面活性剂溶液中胶束的表观摩尔质量 .结果表明 ,随体系中添加物质的不同 ,因胶束界面吸附及增溶作用 ,表观摩尔质量随之发生变化

【Abstract】 The method of measuring measure the molar weights of the micelle by the scatter light is presented. Based on Rayleigh scatter formula, the experimental device is designed, in which the CCD camera system is employed to collect the scattered light caused by the solution,then the signals are sent to the computer to calculate, so the molar weights of the micelle in the surfactant solution can be obtained. The result shows that the molar weight changes with the different accretion used because of different effects of sorbefaclent and increasing solvency.

【关键词】 光散射胶束表观摩尔质量
【Key words】 scattermicellelapparent molar weight
  • 【文献出处】 四川大学学报(自然科学版) ,JOURNAL OF SICHUAN UNIVERSITY (NATURAL SCIENCE EDITION) , 编辑部邮箱 ,2000年04期
  • 【分类号】O647
  • 【被引频次】3
  • 【下载频次】161
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