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N-对甲苯基马来酰亚胺与苯乙烯聚合的研究

Copolymerization of N-P-Methylphenyl Maleimide with Styrene

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【作者】 贺继东阎志佩王娟

【Author】 HE Ji-dong~1, YAN Zhi-pei~1, WANG Juan~2 (1.Colloge of Polymer Science and Engineering, Qingdao Institute of Chemical Technology, Qingdao 266042; 2.Department of Chemistry,Qingdao University Medical College, Qingdao 266021)

【机构】 青岛化工学院高分子科学与工程学院!青岛266042青岛大学医学院化学教研室!青岛266021

【摘要】 乙醇作溶剂 ,考察了引发剂浓度、单体浓度、聚合时间、聚合温度、引发剂类型对N -对甲苯基马来酰亚胺与苯乙烯的共聚活性的影响 ,得到最佳聚合条件。通过GPC分析 ,测得共聚物分子量。通过红外、核磁共振的联合测定 ,证明N -对甲苯基马来酰亚胺与苯乙烯聚合时能有效地打开双键 ,聚合按交替方式进行。

【Abstract】 The activity of copolymerization system of N-p-methylphenyl maleimide with styrene was systematically studied. Ethanol was used as solvent, and the optimum polymerization condition was found of initiator concentration , monomor concentration, polymerization time , polymerization temperature and initiator type. By GPC analysis, the molecular weight of the copolymer was testified. The results of Infra-red and Nuclear Magnetic Resonant analysis showed that the double bond of N-p-methylphenyl maleimide was split when it was polymerized with styrene, and the copolymerization was alternately carried out.

  • 【文献出处】 青岛化工学院学报 ,JOURNAL OF QINGDAO INSTITUTE OF CHEMICAL TECHNOLOGY , 编辑部邮箱 ,2000年03期
  • 【分类号】O631
  • 【被引频次】5
  • 【下载频次】90
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