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强偶合体系弛豫方程组的计算及J偶合对弛豫的影响

THE COMPUTATION OF THE RELAXATION EQUATIONS OF STRONG COUPLING SYSTEM AND THE EFFECT OF J COUPLING ON RELAXATION

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【作者】 许峰黄永仁

【Author】 XU Feng (Dept. of Math. and Phys., Huainan Institute of Technology, Huainan 232001) HUANG Yong ren (NMR Lab., East China Normal University, Shanghai 200062)

【机构】 淮南工业学院数理系!淮南232001华东师范大学分析测试中心!上海200062

【摘要】 根据WBR理论 ,采用“改进的矩阵计算方法” ,计算出了强偶合体系较为完整、准确的弛豫方程组 ,并根据此方程组分析研究了J偶合对横向弛豫、纵向弛豫和交叉弛豫的影响 ,获得了一些相应的结论

【Abstract】 According to the WBR theory and by means of the “Promoted matrix computation method”, the authors computed and studied the relaxation equations of strong coupling system, especially the effect of J coupling on transverse relaxation, longitudinal relaxation and cross relaxation. Finally the authors gained the following valuable conclusions. (1) The effect of weak coupling on the computation of relaxation is very small and neglectable. (2) The strong coupling has hardly any effect on the computation of transverse relaxation. (3) The strong coupling has a certain extern effect on the computation of longitudinal relaxation and cross relaxation, especially this effect achieves maximum when the match condition ω\-a-ω\-b≈2πJ comes into existence and can’t be neglected.

【关键词】 核磁共振弛豫J偶合Solomon方程
【Key words】 NMRRelaxationJ couplingSolomon equati?
【基金】 安徽省教委自然科学基金;淮南工业学院青年基金项目
  • 【文献出处】 波谱学杂志 ,Chinese Journal of Magnetic Resonance , 编辑部邮箱 ,2000年06期
  • 【分类号】O482
  • 【被引频次】5
  • 【下载频次】23
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