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大叶吊兰甙A和B的NMR化学位移全归属
COMPLETE ASSIGNMENT OF NMR CHEMICAL SHIFTS OF CHLOROMALOSIDE A AND B
【摘要】 应用 2DNMR实验技术进一步研究确定了从百合科植物大叶吊兰中分离到的两个新的C 2 7甾体皂甙类化合物 ,大叶吊兰甙 (chloromaloside)A和B的化学结构 ,并对其1 H和1 3CNMR信号进行了全归属 .
【Abstract】 By means of 2D NMR techniques, such as HMQC TOCSY,TOCSY,ROESY,HMQC,HMBC and COSY, the structures of chloromaloside A and B, two new C 27 steroidal saponins from \%Chlorophytum malayense\% were confirmed. Their complete assignment of \{\}\+1H and \{\}\+\{13\}C NMR chemical shifts were also obtained. \;
【关键词】 Chloromaloside A;
Chloromaloside B;
甾体皂甙;
NMR信号全归属;
【Key words】 Steroidal saponins; Chloromaloside A; Chloromaloside B; complete assignment;
【Key words】 Steroidal saponins; Chloromaloside A; Chloromaloside B; complete assignment;
【基金】 中国科学院昆明植物所植物化学开放研究室资助课题
- 【文献出处】 波谱学杂志 ,CHINESE JOURNAL OF MAGNETIC RESONANCE , 编辑部邮箱 ,2000年05期
- 【分类号】O629
- 【被引频次】4
- 【下载频次】80