【摘要】 使用 L KB2 1 0 7型微量热计 -微机数据采集系统测量了 2 88.1 5K、2 98.1 5K、30 8.1 5K下 Li Cl- CH3OH-H2 O体系在不同混合溶剂浓度下的稀释热。测量结果用扩展的 Debye- Hückl方程、Pitzer模型和单参数模型关联。计算了方程中的参数和溶液无限稀释热 -ΔH∞D( m Li Cl=1 mol/ kg)。结果表明 :相同混合溶剂浓度下 ,-Δ H∞D 随温度增加而增加 ;同一温度下 ,- ΔH∞D 随溶剂浓度 x2 ′的增大而增大。更多还原

【Abstract】 Heat of dilution for LiCl/CH₃OH-H₂O system has been measured with LKB 2107 flow microcalorimeter-PC data acquisitor system at 288.15 K,298.15 K and 308.15 K. The experimental results were correlated using the extended form of the Debye-Hückel limiting law, the ion interaction model of Pitzer and the single parameter model. The parameters of each model were correlated, and the molar enthalpies of dilution at infinite dilution of LiCl（m_LiCl=1.0 mol/kg）for fixed composition of the mixed solvent were obtained. The results indicate that ΔH_D∞ increases with temperature at the same concentration of mixed solvents, and ΔH_D∞ increases with the concentration of solvents at the same temperature.更多还原