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两种UHMWPE/Kaolin复合材料在干摩擦条件下的滑动摩擦磨损性能研究

A Study on Friction and Wear Properties of Two Kind UHMWPE/Kaolin Composites under Dry Sliding

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【作者】 龚国芳王新曲敬信漆宗能

【Author】 GONG Guo fang 1, WANG Xin 2, QU Jing xin 1, QI Zong neng 2 (1.Laboratory of Material Engineering, China University of Mining Technology, Beijing 100083; 2.State Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sc

【机构】 中国矿业大学北京校区材料工程研究室!北京100083淮南工业学院机械工程系安徽淮南232001中国科学院化学研究所工程塑料国家重点实验室!北京100080

【摘要】 在 MM- 2 0 0型磨损试验机上分别对以釜内聚合和熔融机械混合方法制备的高岭土填充超高分子量聚乙烯基复合材料 (UHMWPE/ Kaolin)在干摩擦条件下与 45 #钢对摩时的摩擦磨损性能进行了研究 ,并用扫描电子显微镜和立体光学显微镜对其磨损表面进行了观察与分析 ,对材料的磨损机理进行了探讨 .结果表明 :引入适量的高岭土能明显降低 UHMWPE的摩擦系数和磨损率 ,用釜内聚合方法制备的 UHMWPE/ Kaolin复合材料的摩擦系数和磨损率比用机械混合方法制备的同样成分的复合材料的都低 ;2种复合材料均能在偶件钢试环表面形成转移膜 ,从而使复合材料的摩擦系数和磨损率比纯 UHMWPE的均有所降低 .但二者的转移膜特性存在差异 ,这也是 2种复合材料的摩擦磨损性能产生差异的原因之一 ;而聚合型和混合型 UHMWPE/ Kaolin复合材料摩擦系数和磨损率的差异主要取决于其晶体结构的不同

【Abstract】 Kaolin filled ultra high molecular weight polyethylene (UHMWPE) based composites (coded as UHMWPE/Kaolin) were prepared by polymerization filling and melt mixing, respectively. The friction and wear properties of the composites under dry sliding against AISI 1045 steel were evaluated with an MM 200 friction and wear tester. The morphologies of the worn composite surfaces and of the transfer films on the counterface steel were observed by means of scanning electron microscopy (SEM) and stereo optical microscopy. As the results, kaolin at a certain content is very effective to reduce the friction and wear of UHMWPE. UHMWPE/Kaolin composites prepared by polymerization filling are superior to the ones prepared by melt mixing with the same filler content in terms of friction reduction and reducing wear. The differences in the transfer film characteristics and the structure of UHMWPE account for the different friction and wear properties of the two kind composites.

【基金】 国家自然科学基金! ( 5 983 3 3 10 )
  • 【分类号】TB33
  • 【被引频次】17
  • 【下载频次】185
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