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二氧化硅在两种摩擦条件下的摩擦性能及其机理研究

Investigations of the Friction Behavior of SiO2 under Dry Sliding and Lubrication

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【作者】 张文光杨生荣刘维民薛群基刘承业

【Author】 ZHANG Wen guang 1, YANG Sheng rong 1, LIU Wei min 1, XUE Qun ji 1, LIU Cheng ye 2 (1.State Key Laboratory of Solid Lubrication,Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000, China; 2.Department of Mechanic

【机构】 中国科学院兰州化学物理研究所固体润滑国家重点实验室!甘肃兰州730000中国科学院兰州化学物理研究所固体润滑国家重点实验室!甘肃兰

【摘要】 利用 SRV摩擦磨损试验机及静动摩擦系数测定仪考察了 Si O2 陶瓷 / GCr1 5钢摩擦副在干摩擦及水、正丁醇、正癸醇和正辛酸等润滑下的摩擦性能 .结果表明 ,小振幅往复摩擦磨损条件下的摩擦系数顺序为 :干摩擦 >水 >正丁醇 >正癸醇≈正辛酸 ;静动摩擦条件下摩擦系数顺序为 :水 >正丁醇 >正癸醇 >干摩擦 >正辛酸 .利用 DSC对润滑剂同 Si O2 之间的反应活性进行了模拟考察 .发现润滑剂同陶瓷表面之间的反应活性越高 ,摩擦系数越高 .反应活性顺序为 :水 >正丁醇 >正癸醇 >正辛酸 ,摩擦化学反应膜的特性对摩擦学性能都具有重要影响 .

【Abstract】 The friction behavior of SiO 2/GCr15 in dry air and lubricated with distilled water, 1 butanol,1 decanol and octanoic acid was investigated using SRV ball on disk test rig and a Kyowa DF·PM one way reciprocating friction tester. The reactivity between the lubricants and SiO 2 surface was simulated by differential scanning calorimetry (DSC). As the results, the order of the friction coefficient under oscillating condition can be ranked as dry air>distilled water>1 butanol>1 decanol≈octanoic acid, that under one way reciprocating condition can be ranked as distilled water>1 butanol>1 decanol>dry air≈octanoic acid. The order of the reactivity between the lubricants and SiO 2 surface is distilled water>1 butanol>1 decanol>octanoic acid. Thus the higher the reactivity between the lubricants and SiO 2 surface, the higher the friction coefficient will be. The characteristics of the tribochemical reaction film could play an important role in governing the friction behavior of SiO 2 ceramic.

【关键词】 SiO2陶瓷摩擦润滑机理
【Key words】 SiO 2 ceramicfriction behaviorlubrication mechanism
【基金】 国家自然科学基金资助项目! ( 5970 2 0 0 1 );中国科学院基础局资助重点项目! ( KJ952 -51 50 9)
  • 【分类号】TH117
  • 【被引频次】3
  • 【下载频次】226
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