【摘要】 以苯和三氯化磷等小分子化合物为原料，合成制备了固体酸催化剂磺化苯膦酸锆，用红外光谱、X-射线衍射方法对其结构表征，并研究其在酯化反应中的催化活性。实验结果表明：磺化苯膦酸锆是一种具有层状结构的活性较高的固体酸催化剂，乙酸丁酯，氯乙酸丁酯反应温度控制在110~120℃，产物收率在80%以上，催化剂重复使用多次后用稀酸浸泡可恢复活性。更多还原

【Abstract】 The sulphonated zirconium bis(benzenephosphonate) was synthesized from benzene and phosphorus trichloride and other substances. Its structure was characterized by IR and X-ray diffraction analysis. And its catalytic properties in esterification reaction were studied.更多还原