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间接原子吸收光谱法测定工业废水中痕量二硫化碳
INDIRECT DETERMINATION OF TRACE AMOUNTS OF CARBON DISULFIDE IN WASTE WATER BY AAS
【摘要】 研究了用二硫代氨基甲酸银间接原子吸收光谱法测定工业废水中二硫化碳。线性范围为 2~ 30μg· ml-1,检出限为 1 .0 2μg· ml-1,回收率为 96%~ 1 0 6% ;且 H2 S和 Cu( )等不干扰测定。方法适用于工业废水中二硫化碳的测定 ,结果满意
【Abstract】 An indirect AAS determination of carbon disulfide in waste water is described in this paper. In an alkaline medium, CS 2 reacts with diethylamine to form DDTC which is further reacted with Ag + to form AgDDTC. The trace amount of CS 2 is determined indirectly by the determination of Ag(Ⅰ) by AAS. A linear relationship holds in the range of 2~30μg of CS 2 per ml. and the limit of detection for CS 2 is 1.02μg·ml -1 . The presence of H 2S and Cu(Ⅱ) do not interfere with the determination.
- 【文献出处】 理化检验(化学分册) ,Physical Testing and Chemical Analysis Partb Chemical Analgsis , 编辑部邮箱 ,2000年04期
- 【分类号】X832
- 【被引频次】2
- 【下载频次】82