节点文献

脂肪腈一步法制双脂肪烃基仲胺新工艺的研究

One-step Preparation of Fatty sec-Amines from Fatty Nitriles

  • 推荐 CAJ下载
  • PDF下载
  • 不支持迅雷等下载工具,请取消加速工具后下载。

【作者】 张文楠赵林庞世毅

【Author】 ZHANG Wen-nan,ZHAO Lin,PANG Shi-yi (He′nan Institute of Chemistry,He′nan Academy of Sciences,Zheng zhou 450002,China)

【机构】 河南省科学院化学研究所!河南郑州450002

【摘要】 采用合成氨厂的氨合成气代替纯氢气使脂肪腈加压催化氢化 ,可一步制得双脂肪烃基仲胺。采用该工艺制得的仲胺产品质量技术指标为 :w(仲胺 ) =92 % ,w(叔胺 ) <3% ,总胺值 =110mgKOH/g ,达到美国Kemanines - 970和日本FarminB62等同类产品水平。

【Abstract】 Fatty sec-amines can be directly prepared by catalytic h ydrogenation of fatty nitriles,using ammonia synthesis gas instead of pure hydro gen.Major qualities of the sec-amines produced by the new processes were w (sec-amines)=92%,w(tert-amines)<3%,total amines=110 mgKOH/g ,comparable to the similar products prepared by the conventional processes,for e xa mple (USA)Kemanines-970 and (Japan)Farmin B62.Experiment showed that this new pr ocess has many advantages such as simple procedure,save of investment,lower cost,etc.

【关键词】 仲胺脂肪腈氨合成气
【Key words】 fatty nitrilesec-amineammonia synthesis gas
  • 【分类号】TQ423
  • 【被引频次】1
  • 【下载频次】120
节点文献中: 

本文链接的文献网络图示:

本文的引文网络