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改性片麻岩为催化剂合成有机羧酸酯的研究
Synthesis of Organic Carboxylate Using Modified Gnarl Catalyst
【摘要】 以改性片麻岩为催化剂合成了醋酸乙酯、醋酸丁酯、醋酸戊酯、醋酸庚酯、醋酸苄醇酯、己酸乙酯、氯乙酸异丙酯和丙烯酸 2 乙基 己醇酯 ,其收率都在 90 %以上。合成醋酸丁酯 ,催化剂重复使用 9次 ,其收率仍达 92 %~ 99% ;催化剂的寿命达 489h ,醋酸丁酯收率仍不低于 92 %。
【Abstract】 Ethyl acetate,n butyl acetate,n amyl acetate,n heptyl acetate,benzyl acetate,ethyl hexanoate,isopropyl chloroacetate and 2 ethylhexyl acrylate were synthesized using modified gnarl catalyst.Yields of all esters were above 90%.When the catalyst was repeatedly used for 9 times,the yield of n butyl acetate still reached 92%-99%.At a catalyst life of 489 h,the yield of n butyl acetate was not less than 92%.
【关键词】 改性片麻岩;
催化酯化;
有机羧酸酯;
【Key words】 modified gnarl; catalytical esterification; organic carboxylate;
【Key words】 modified gnarl; catalytical esterification; organic carboxylate;
- 【文献出处】 精细化工 ,FINE CHEMICALS , 编辑部邮箱 ,2000年05期
- 【分类号】TQ426
- 【被引频次】5
- 【下载频次】63